Resumo (PT):
Abstract (EN):
This work reviews the state-of-the-art nanostructured photoelectrodes for use in dye-sensitized solar
cells. The influence of the photoelectrode structure in the DSC performance is analyzed. The
nanostructured photoelectrodes can be classified into: (1) nanoparticles with high surface areas for
efficient dye loading; (2) 1D nanostructures such as nanotubes and nanowires that offer direct electron
transport pathways towards the collecting substrate; (3) 3D hierarchically ordered photoelectrodes that
combine large pores for efficient electrolyte diffusion, large particles for effective light scattering but also
small particles needed to achieve high surface areas; (4) 3D template-based techniques that create highly
conductive macroporous scaffolds to produce structures with different length scales for electrolyte
diffusion (macro and mesopores) and dye loading (micro and nanopores); and finally (5) hybrid TiO2/
graphene nanostructures able to suppress electron recombination in the semiconductor/electrolyte
interface, increasing the electron mobility and extraction and also able to enhance light absorption,
ultimately increasing the DSC performance.
Idioma:
Inglês
Tipo (Avaliação Docente):
Científica
Notas:
Publicação abrangida pelo Journal Citation Reports 2015
Nº de páginas:
16